Nanotube Radio
Did Marconi invent radio the wrong way?
Making a mockery of the complex architecture of wireless
transmission, a single molecule of carbon nanotube performs
all the functions of a wireless Radio! Being only a few
billionths of a meter in size, the nanotube radio is so small it
can easily fit inside a living cell or float about in your
bloodstream. In fact, it is about the size of a virus. Nanotubes
are a better conductor of electricity than copper, silver or even
superconductors! The science of miniaturization is indeed
venturing into the eerie vista of infinitesimally small

Looks like we have been making radios the wrong way, piecing together
complex circuitry with its hundreds of components, while nature had already
configured a few atoms of carbon to do the job most brilliantly. The situation is
akin to a supercomputer which, with all its complexity, size and tremendous
energy consumption, compares pitiably with the size and efficiency of human
brain.
























The conventional radio essentially comprises four parts: antenna, tuner,
amplifier, and demodulator as shown in the block diagram. The antenna
collects radio signals from the surrounding and together with a tuner selects
the desired frequency. The weak signal so selected is then handed over to an
amplifier which amplifies the signal. Next comes demodulation; the process of
extracting information from the career signal. This information, the audio
program in this case, is further amplified and fed to a speaker which converts
electrical pulses into sound waves; speech, song, music, etc. It involves
thousands of components and, as compared to a carbon nanotube, is housed
in a huge box. And of course the traditional radio consumes thousands of
times more energy than its nano counterpart.

The Nanotube Radio

Carbon Nanotubes are tubular structures of molecular scale and are among
the stiffest and strongest fibers known. The force that binds the atoms of
carbon together in a nanotube is the strongest in nature. They also have
remarkable electronic properties and many other unique characteristics.
Nanotubes are a better conductor of electricity than copper, silver or even
superconductors. The stable and strong structure of carbon in graphite and
diamond led to speculations that this element could be molded into even more
stronger and stable microstructures. The research in this area resulted in the
discovery of nanotubes in 1999. These tubes can be single layered or
multilayered. The outer diameter of a multilayer nanotube ranges from 3
nanometer to 30 nanometer but the diameter of a typical single layer nanotube
has a diameter of 1-2 nanometer s. A single layer nanotube may be
considered as a sheet of graphite rolled into a hollow tube, without any
overlapping where the two edges meet.















A team of researchers at UC Berkeley lead by physicist Alex Zettl have
invented a radio made of a single carbon nanotube. Zettl was interested in
making tiny sensors capable of communicating with one another wirelessly.
During the course of investigation, it was found that a nanotube fixed to some
base at one end could be made to vibrate if hit by molecules at its free end.
The frequency of vibration depended on the mass of hitting molecules. Zettl
further noticed that the nanotube could be made to vibrate at frequencies
used by commercial radio transmissions. It was here that the idea of creating a
radio at nanoscale germinated. The radio that resulted was small enough to fit
inside a living cell and was capable of performing all the functions of a
conventional radio with astonishing simplicity.

The Mysterious Realm of Nano-world

A conventional radio picks signals through its antenna tuned to the frequency
to be selected. Due to the phenomenon of resonance, a small current is
induced in the antenna by the selected frequency. The process is electronic.
By contrast, the process of capturing the signal is physical in the nanotube
radio. The nanotube is so small that when it is hit by the incoming
electromagnetic signal in a suitable environment, it starts vibrating physically in
tune with the electromagnetic wave.
In the original experiment by Zettl and his team, a multi-walled nanotube was
grown on a tiny electrode. Some distance apart from nanotube was a counter-
electrode. A small DC voltage applied across the electrodes caused electrons
to flow from the tip of the nanotube to the counter-electrode. When hit by an
electromagnetic signal, the nanotube starts vibrating physically causing a
change in the current flowing between the tiny electrodes. This is called a field
emission current. In this phenomenon of quantum mechanics, a small applied
voltage produces a large flow of current from the tip of an object. In this case,
the flow of current is in sync with the electromagnetic waves hitting the
nanotube. The nanotube thus functions both as an antenna and as an
amplifier for the detected signal. You would, however, need speakers or
earphones to hear the transmission.
But how do you tune a nanotube for different frequencies? As mentioned
earlier, unlike a conventional antenna that resonates electronically in
response to an electromagnetic wave, a nanotube vibrates physically under
the direct physical impact of the electromagnetic waves hitting it. It was only
natural to expect that the frequency a nanotube could be changed physically
which is indeed the case. The frequency of a nanotube can be altered exactly
as you physically change the frequency of a string of guitar. There are two
ways of doing it. By increasing or decreasing the length of the guitar string or
by increasing or decreasing the tension in the string. In the case of a
nanotube however, the process of changing the frequency by changing its
length is irreversible and is thus not a useful option. Tempering with the
tension in the nanotube is easier. The tension in a nanotube is increased or
decreased by varying the strength of the electric field in which the nanotube is
placed. This change in tension also changes its frequency. When the
frequency of nanotube is fixed by tweaking the strength of the applied electric
field, the nanotube will vibrate only if electromagnetic waves of exactly the
same frequency are hitting the nanotube. By adjusting the frequency of the
nanotube, one can make it vibrate in sync with the desired electromagnetic
signal (radio transmission).
Next comes demodulation; the process of extracting information (program)
from the career wave. In conventional AM radio, this is accomplished by
rectification and filtering the signal whereby the career wave is not allowed to
pass and only the variations in amplitude (information) is passed on. By a
stroke of luck, this is also achieved naturally by the nanotube. When it vibrates
in response to an electromagnetic signal, the current coming out of the
nanotube varies with the coded (informational) signal embedded within the
career. By a string of highly favorable attributes of a nanotube, all the vital
functions of a radio are performed by it single handedly. A nanotube:
•        can be tuned to radio frequencies
•        detects the electromagnetic signal
•        amplifies the signal
•        separates information from the career signal
In the words of Zettl,
“In electronics, often you have a trade off. If you optimize this, you lose
something else. Here [in the case of nanotube radio] everything seems to just
work for you, which is a little unusual. You don’t see that often in science. It is
one of those rare opportunities to see Murphy’s Law not rearing its ugly head.
Here everything that can go right is going right.”
Zettl and his colleagues believe that there will be many applications for the
radio. It could be used in medical devices that swim through your body,
responding to radio commands. Or it could be put inside tiny wireless devices.
It could even be put inside a human ear.
Article, Sana Haq  (Apr 2011)
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Multi Layer Nanotube
Nanotube Like a Folded Sheet of Graphehe

                        Carbon Nanotubes

Carbon nanotubes are molecular-scale tubes of graphitic
carbon with outstanding properties. They are among the
stiffest and strongest fibers known, and have remarkable
electronic properties along with many other unique
characteristics. For these reasons they have attracted huge
academic and industrial interest. Commercial applications
have been rather slow to develop, however, primarily because
of the high production costs of the best quality nanotubes.

The discovery that carbon could form stable, ordered
structures other than graphite and diamond stimulated
researchers worldwide to search for other new forms of
carbon. The search was given new impetus when it was shown
in 1990 that C60 could be produced in a simple arc-
evaporation apparatus readily available in all laboratories. It
was using such an evaporator that the Japanese scientist
Sumio Iijima discovered fullerene-related carbon nanotubes in
1991. The tubes contained at least two layers, often many
more, and ranged in outer diameter from about 3 nm to 30
nm. They were invariably closed at both ends.

In 1993, a new class of carbon nanotube was discovered, with
just a single layer. These single-walled nanotubes are
generally narrower than the multi-walled tubes, with diameters
typically in the range 1-2 nm, and tend to be curved rather
than straight. It was soon established that these new fibers
had a range of exceptional properties which encouraged
research in this field.

The bonding in carbon nanotubes is sp², with each atom
joined to three neighbors, as in graphite. The tubes can
therefore be considered as rolled-up graphene sheets
(graphene is an individual graphite layer). There are three
distinct ways in which a graphene sheet can be rolled into a
tube.
The arc-evaporation method, which produces the best quality
nanotubes, involves passing a current of about 50 amps
between two graphite electrodes in an atmosphere of helium.
This causes the graphite to vaporize, some of it condensing
on the walls of the reaction vessel and some of it on the
cathode. It is the deposit on the cathode which contains the
carbon nanotubes. Single-walled nanotubes are produced
when Co and Ni or some other metal is added to the anode. It
has been known since the 1950s that carbon nanotubes can
also be made by passing a carbon-containing gas, such as a
hydrocarbon, over a catalyst. The catalyst consists of nano-
size particles of metal, usually Fe, Co or Ni. These particles
catalyze the breakdown of the gaseous molecules into carbon,
and a tube then begins to grow with a metal particle at the tip.
It was shown in 1996 that single-walled nanotubes can also be
produced catalytically. The perfection of carbon nanotubes
produced in this way has generally been poorer than those
made by arc-evaporation, but great improvements in the
technique have been made in recent years.

The big advantage of catalytic synthesis over arc-evaporation
is that it can be scaled up for volume production. The third
important method for making carbon nanotubes involves using
a powerful laser to vaporize a metal-graphite target. This can
be used to produce single-walled tubes with high yield.
The strength of the sp² carbon-carbon bonds gives carbon
nanotubes amazing mechanical properties. The stiffness of a
material is measured in terms of its Young's modulus, the rate
of change of stress with applied strain. The Young's modulus
of the best nanotubes can be as high as 1000 GPa which is
approximately 5x higher than steel. The tensile strength, or
breaking strain of nanotubes can be up to 63 GPa, around
50x higher than steel. These properties, coupled with the
lightness of carbon nanotubes, give them great potential in
applications such as aerospace. It has even been suggested
that nanotubes could be used in the “space elevator”, an
Earth-to-space cable first proposed by Arthur C. Clarke. The
electronic properties of carbon nanotubes are also
extraordinary. Especially notable is the fact that nanotubes
can be metallic or semiconducting depending on their
structure. Thus, some nanotubes have conductivities higher
than that of copper, while others behave more like silicon.

There are several areas of technology where carbon
nanotubes are already being used. These include flat-panel
displays, scanning probe microscopes and sensing devices.
The unique properties of carbon nanotubes will undoubtedly
lead to many more applications.
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